A facile approach to prepare biomass-derived activated carbon hollow fibers from wood waste as high-performance supercapacitor electrodes

被引:54
|
作者
Ma, Xiaojun [1 ]
Ding, Chenfeng [2 ]
Li, Dongna [1 ]
Wu, Mingyue [1 ]
Yu, Yunhua [2 ]
机构
[1] Tianjin Univ Sci & Technol, Dept Wood Sci & Technol, Tianjin 300222, Peoples R China
[2] Beijing Univ Chem Technol, Coll Mat Sci & Engn, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
Wood waste; Activated carbon hollow fibers; Supercapacitors; Half-curing; Liquefaction; NITROGEN; ENERGY; ADSORPTION; CHARCOAL;
D O I
10.1007/s10570-018-1903-3
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
In this paper, several activated carbon hollow fibers (ACHF) with high surface area of similar to 1873 m(2) g(-1) were prepared from wood waste by liquefaction, half-curing and one-step activation methods. Scanning electron microscopy, Nitrogen gas adsorption-desorption and X-ray photoelectron spectroscopy have been used to characterize the morphology, the structure and the composition of ACHF. Results show added wood charcoal had a noticeable influence on the pore structure and electrochemical performance of ACHF. Electrochemical investigation measurements show that ACHF exhibit an outstanding specific capacitance (295 F g(-1) at 0.5 A g(-1)), excellent rate performance (73.8% capacitance retention at 20 A g(-1)), high energy density (7.8 W h kg(-1)) and high capacitance retention of 99.5% over 10,000 charge-discharge cycles. Moreover, the multiple heteroatoms (N, P) from wood liquefaction have a synergistic effect on electrochemical properties of ACHF. These results indicate the present method is promising for the preparation of biomass-derived activated carbon hollow fibers from agricultural and forestry waste in the application of supercapacitors. [GRAPHICS] .
引用
收藏
页码:4743 / 4755
页数:13
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