Lithium perchlorate (tetrafluoroborate)-diethyl carbonate-propylene carbonate electrolyte systems

被引:3
|
作者
Varlamova, T. M. [1 ]
Yurina, E. S. [1 ]
机构
[1] Saratov NG Chernyshevskii State Univ, Saratov 410601, Russia
来源
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2006年 / 80卷 / 08期
关键词
D O I
10.1134/S0036024406080164
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The method of sections was used to study the solubility of the components of the LiClO4 (LiBF4)-diethyl carbonate (DEC)-propylene carbonate (PC) ternary system at 25 degrees C. The phase diagrams of the systems were plotted and discussed. At this temperature, the solid phase of the LiClO4-DEC-PC system is pure salt while that of the LiBF4-DEC-PC system is composed of LiBF4 and its LiBF4 center dot DEC and LiBF4 center dot PC crystal solvates. The compositions of the crystallized solid phases obtained graphically by using the method of sections were confirmed by XRD analysis.
引用
收藏
页码:1265 / 1268
页数:4
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