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Sc(OTf)3-catalyzed three-component reactions of aldehydes, amines and allyltributylstannane in micellar systems.: Facile synthesis of homoallylic amines in water
被引:122
|作者:
Kobayashi, S
[1
]
Busujima, T
Nagayama, S
机构:
[1] Sci Univ Tokyo, Fac Sci, Dept Appl Chem, Shinjuku Ku, Tokyo, Japan
[2] Japan Sci & Technol Corp, CREST, Shinjuku Ku, Tokyo, Japan
关键词:
D O I:
10.1039/a706498e
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Three-component reactions of aldehydes, amines and allyltributylstannane proceeded smoothly in water without using any organic solvents, in the presence of a small amount of scandium trifluoromethanesulfonate [Sc(OTf)(3)] and sodium dodecylsulfate (SDS), to afford the corresponding homoallylic amines in high yields.
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页码:19 / 20
页数:2
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