Oxidation of cumene in the presence of the benzoyl peroxide-tetraalkylammonium iodide initiator system

被引：0

作者：

Opeida, IA ^{[1
]}

Zalevskaya, NM ^{[1
]}

Turovskaya, EN ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, Litvinenko Inst Physicoorgan & Coal Chem, Donetsk, Ukraine

来源：

PETROLEUM CHEMISTRY | 2004年 / 44卷 / 05期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It is found that the benzoyl peroxide-tetraalkylammonium iodide system is an effective initiator of low-temperature liquid-phase oxidation of cumene. The kinetics of this process was studied, and rate equations were obtained. It was shown that the benzoic acid, cumene hydroperoxide, and iodine that are produced in the course of the reaction decrease the oxidation rate.

引用

页码：328 / 333

页数：6

共 37 条

[1] Benzoyl peroxide-tetraalkylammonium iodide system as an initiator of the low-temperature oxidation of cumene
Opeida, IA
Zalevskaya, NM
Turovskaya, EN
KINETICS AND CATALYSIS, 2004, 45 (06) : 774 - 780
[2] Oxidation of cumene with oxygen in the presence of the benzoyl peroxide-tetraalkylammonium bromide low-temperature initiator system
Opejda, I.A.
Zalevskaya, N.M.
Turovskaya, E.N.
Sobka, Yu.I.
Neftekhimiya, 2002, 42 (06): : 460 - 466
[3] Oxidation of cumene with oxygen in the presence of the benzoyl peroxide-tetraalkylammonium bromide low-temperature initiator system
Opeida, IA
Zalevskaya, NM
Turovskaya, EN
Sobka, YI
PETROLEUM CHEMISTRY, 2002, 42 (06) : 423 - 428
[4] Benzoyl peroxide—tetraalkylammonium iodide system as an initiator of the low-temperature oxidation of cumene
I. A. Opeida
N. M. Zalevskaya
E. N. Turovskaya
Kinetics and Catalysis, 2004, 45 : 774 - 780
[5] Benzoyl peroxide—tetraalkylammonium iodide system as an initiator of the low-temperature oxidation of cumene
I. A. Opeida
N. M. Zalevskaya
E. N. Turovskaya
Kinetics and Catalysis, 2004, 45 (6) : 774 - 780
[6] Initiating Properties of Benzoyl Peroxide–Tetraalkylammonium Iodide System in Radical Chain Oxidation Reactions
I. A. Opeida
N. M. Zalevskaya
E. N. Turovskaya
Theoretical and Experimental Chemistry, 2003, 39 (4) : 242 - 246
[7] BENZOYL PEROXIDE AS AN INITIATOR FOR HYDROCARBON OXIDATION
HAMMOND, GS
NANDI, US
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (05) : 1213 - &
[8] SOLVENT EFFECTS AND INITIATOR EFFICIENCY IN THE BENZOYL PEROXIDE-DIMETHYLANILINE SYSTEM
WALLING, C
INDICTOR, N
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (21) : 5814 - 5818
[9] The 18-Crown-6–Benzoyl Peroxide–KBr Supramolecular System in the Initiation of Homolytic Chain-Radical Cumene Oxidation
I. A. Opeida
N. A. Turovskii
N. V. Maksyuta
A. I. Pomeshchenko
Kinetics and Catalysis, 2001, 42 : 613 - 614
[10] The 18-crown-6-benzoyl peroxide-KBr supramolecular system in the initiation of homolytic chain-radical cumene oxidation
Opeida, IA
Turovskii, NA
Maksyuta, NV
Pomeshchenko, AI
KINETICS AND CATALYSIS, 2001, 42 (05) : 613 - 614

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