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Acid-Base Bifunctional Microporous Organic Nanotube Networks for Cascade Reactions
被引:15
|作者:
Wang, Tianqi
[1
]
Xu, Yang
[1
]
He, Zidong
[1
]
Zhang, Hui
[1
]
Xiong, Linfeng
[1
]
Zhou, Minghong
[1
]
Yu, Wei
[1
]
Shi, Buyin
[1
]
Huang, Kun
[1
]
机构:
[1] East China Normal Univ, Sch Chem & Mol Engn, Shanghai 200241, Peoples R China
基金:
中国国家自然科学基金;
关键词:
acid-base bifunctional microporous organic nanotube networks;
hyper-crosslinking core-shell bottlebrush copolymers;
one-pot cascade reactions;
postfunctionalization;
HETEROGENEOUS CATALYSIS;
SILICA NANOPARTICLES;
MESOPOROUS SILICA;
TANDEM CATALYSIS;
POROUS POLYMERS;
METAL SITES;
SHELL;
CORE;
NANOREACTOR;
FRAMEWORK;
D O I:
10.1002/macp.201600431
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
In this paper, the acid-base bifunctional microporous organic nanotube networks (MONNs-SO3H-NH2) are successfully prepared by combination of hyper-crosslinking core-shell bottlebrush copolymers and a postfunctionalization strategy. Based on the large surface area, good multi-porosity interconnectivity, and robust organic frameworks, the acid-base bifunctional MONNs catalyst shows a high catalytic activity and excellent reusability for one-pot cascade reactions.
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页数:7
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