Oxidation of activated aluminum with water as a method for hydrogen generation

被引：29
|
作者：
Parmuzina, A. V. [1 ,2 ]
Kravchenko, O. V. [1 ]
Bulychev, B. M. [1 ]
Shkol'nikov, E. I. [2 ]
Burlakova, A. G. [3 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
[2] Russian Acad Sci, Joint Inst High Temp, Moscow 125412, Russia
[3] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2009年 / 58卷 / 03期
关键词：
activated aluminum; gallium; indium; zinc; tin; gallams; alloys; water; oxidation kinetics; METAL;
D O I：
10.1007/s11172-009-0045-z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The activation of aluminum with low-melting gallium-based alloys makes it possible to obtain a material easily oxidizable by water at room temperature to release similar to 1.2 L of pure hydrogen per 1 g of metal. The kinetics and regularities of the interaction of activated aluminum with water were studied as a function of the amount and composition of metal activators, dispersity of the powder, and temperature. The phase composition of the solid reaction products was shown by X-ray diffraction analysis to depend on temperature and duration of the process.
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页码：493 / 498
页数：6
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