Synthesis of a copper (II) metal-organic framework for photocatalytic degradation of rhodamine B dye in water

被引:41
|
作者
Samuel, Melvin S. [1 ]
Savunthari, Kirankumar Venkat [2 ]
Ethiraj, Selvarajan [3 ]
机构
[1] Indian Inst Technol, Sch Environm Sci & Engn, Kharagpur 721302, W Bengal, India
[2] Kaohsiung Med Univ, Nano & Green Analy Lab, Dept Med & Appl Chem, Kaohsiung 807, Taiwan
[3] SRM Inst Sci & Technol, Sch Bioengn, Dept Genet Engn, Chennai 603203, Tamil Nadu, India
关键词
Metal– organic framework; Hydrothermal method; Photocatalytic activity; Rhodamine B; Visible light; GRAPHENE OXIDE; CATALYTIC-ACTIVITY; AQUEOUS-SOLUTION; MALACHITE GREEN; ADSORPTION; REMOVAL; COMPOSITE; NANOCOMPOSITE; NANOPARTICLES; CU-3(BTC)(2);
D O I
10.1007/s11356-021-13571-9
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The Cu(II) metal-organic frameworks (MOFs) based on 1,3,5-benzenetricarboxylic acid (Cu-3(BTC)(2)) was synthesized by the hydrothermal method. The synthesized Cu-3(BTC)(2) exhibited pyramid-shaped morphology and showing an average specific area of 32.16 m(2) g(-1). The Cu-3(BTC)(2) photocatalysts were characterized using Fourier-transform infrared spectroscopy (FTIR), powder X-ray diffraction (PXRD), field emission scanning electron microscopy-energy-dispersive X-ray spectroscopy (FESEM-EDX), UV-Vis diffusive reflectance spectra, and Brunauer-Emmett-Teller (BET). The photocatalytic activity of Cu-3(BTC)(2) was examined on Rhodamine B (RhB) degradation under visible light irradiation. The outcomes displayed exceedingly enhanced photocatalytic activity under visible light. In addition, its recyclability was also confirmed for multiple cycles. The easiness of construction and high photocatalytic performance of Cu-3(BTC)(2) photocatalysts can be capable in environmental applications to treat water contamination.
引用
收藏
页码:40835 / 40843
页数:9
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