Proton Exchange Membranes Based on Polymeric Ionic Liquids for Fuel Cell Applications

被引：7
|
作者：
Sainz De Aja, A. Ortiz [1 ]
Diaz Vejo, M. [1 ]
Ortiz Uribe, I. [1 ]
机构：
[1] Univ Cantabria, Dept Chem & Biomol Engn, E-39005 Santander, Spain
来源：
POLYMER ELECTROLYTE FUEL CELLS 16 (PEFC 16) | 2016年 / 75卷 / 14期
关键词：
ELECTROLYTE MEMBRANES; COMPOSITE;
D O I：
10.1149/07514.0589ecst
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Proton Exchange Membrane Fuel Cells (PEMFCs) are being considered as a promising energy source due to their high energy efficiency and low environmental impact. The proton exchange membrane, which is the key component of a PEMFC, needs a considerable improvement regarding its performance without external humidification. Concerning this aspect, many authors are working incorporating ionic liquids as proton exchange components in PEMFCs. In this work, polymeric ionic liquids have been designed for their use as electrolytes without external humidification. For this purpose, membranes based on [HSO(3)BVIm][ TfO]/[HSO3-BMIm][TfO] and [SBMIm][SEM]/[SBVIm][SEM] were developed for H-2/air proton exchange membrane fuel cells working without external humidification. Fuel cell tests and ionic conductivity experiments show the great potential of these ionic liquid-based polymers as proton exchange membranes.
引用
收藏
页码：589 / 596
页数：8
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