Anomalous ferromagnetic behavior of CuO nanorods synthesized via hydrothermal method

被引:74
|
作者
Xiao, Hong-Mei
Zhu, Lu-Ping
Liu, Xian-Ming
Fu, Shao-Yun [1 ]
机构
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
基金
中国国家自然科学基金;
关键词
chemical synthesis; nanorods; exchange and superexchange;
D O I
10.1016/j.ssc.2006.12.005
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Copper monoxide (CuO) nanorods of 30-40 nm in diameter and 100-200 nm in length were successfully synthesized using a hydrothermal reaction method in the presence of sodium citrate. On the basis of the morphology observation and X-ray diffraction patterns of the samples, a possible growth mechanism of the CuO nanorods was proposed. The magnetic properties of CuO nanorods were studied using a SQUID magnetometer and a vibrating sample magnetometer. It was interesting to note that the as-synthesized CuO nanorods showed an anomalous ferromagnetic behavior. The coercive force (H-C) for the CuO nanorods at T = 5 K and T = 300 K were estimated to be 331.39 and 175.88 Oe, respectively. The anomalous ferromagnetic behavior of the as-synthesized CuO nanorods was discussed in terms of the effect of the peculiar morphology. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:431 / 435
页数:5
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