Anion-Responsive π-Electronic Systems Providing Ion-Pairing Assemblies

被引：2
|
作者：
Haketa, Yohei [1 ]
Yamakado, Ryohei [1 ]
Maeda, Hiromitsu [1 ]
机构：
[1] Ritsumeikan Univ, Coll Pharmaceut Sci, 1-1-1 Nojihigashi, Kusatsu 5258577, Japan
来源：
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2016年 / 74卷 / 03期
关键词：
pi-electronic systems; pyrrole derivatives; 1,3-diketones; boron compounds; anion binding; ion pairs; interionic interactions; supramolecular assemblies; soft materials; SUBSTITUTED C-3-BRIDGED OLIGOPYRROLES; CIRCULARLY-POLARIZED LUMINESCENCE; POTENTIAL BUILDING SUBUNITS; SUPRAMOLECULAR ASSEMBLIES; BF2; COMPLEXES; PLANAR; RECEPTOR; DIPYRROLYLDIKETONES; BLOCKS; FORM;
D O I：
10.5059/yukigoseikyokaishi.74.243
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A variety of anion-responsive pi-electronic systems (anion receptors) based on a 1,3-dipyrrolylpropane-1,3-dione framework have been synthesized. The anion receptors form complexes with anions, affording diverse modes including [1+1]-type planar complexes. Anion complexes of the pi-electronic systems form ion pairs with cationic species, resulting in assembled structures. Through interionic interactions and other noncovalent interactions, ion-pairing assemblies construct ordered structures in bulk materials such as crystals, supramolecular gels, and thermotropic liquid crystals, exhibiting fascinating electronic properties including semiconductive behaviors.
引用
收藏
页码：243 / 253
页数：11
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