Preparation of Monodisperse Bio-Based Polymer Particles via Dispersion Polymerization

被引：5
|
作者：
Onita, Katsuhiro [1 ]
Onishi, Miku [1 ]
Omura, Taro [1 ]
Wakiya, Takeshi [2 ]
Suzuki, Toyoko [1 ]
Minami, Hideto [1 ]
机构：
[1] Kobe Univ, Grad Sch Engn, Dept Chem Sci & Engn, Kobe, Hyogo 6578501, Japan
[2] Sekisui Chem Co Ltd, Res & Dev Inst, High Performance Plast Co, Osaka 6180021, Japan
来源：
LANGMUIR | 2022年 / 38卷 / 23期
关键词：
EMULSION POLYMERIZATION; METHYLENE; COPOLYMERIZATION; BUTYROLACTONE; SIZE; OIL;
D O I：
10.1021/acs.langmuir.2c00946
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Monodisperse bio-based polymer particles were successfully prepared through the dispersion polymerization of tulip-derived alpha-methylene-gamma-butyrolactone (MBL) in N,N-dimethylformamide/ethanol (7/3, w/w) at 65 degrees C with poly(vinylpyrrolidone) (PVP) as a colloidal stabilizer. The diameter of the polymer particles was well controlled by changing the composition of the reaction medium or PVP concentration. Furthermore, 100% bio-based poly(MBL) (PMBL) particles were prepared via the dispersion polymerization of MBL in water using hydrolyzed PMBL as a colloidal stabilizer, which was synthesized by hydrolysis of PMBL.
引用
收藏
页码：7341 / 7345
页数：5
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