Characterization of the [3Fe-4S]0/1+ cluster from the D14C variant of Pyrococcus furiosus ferredoxin via combined NRVS and DFT analyses

被引：8
|
作者：
Lauterbach, Lars [1 ,2 ]
Gee, Leland B. [1 ]
Pelmenschikov, Vladimir [2 ]
Jenney, Francis E., Jr. [3 ]
Kamali, Saeed [1 ,4 ]
Yoda, Yoshitaka [5 ]
Adams, Michael W. W. [6 ]
Cramer, Stephen P. [1 ,7 ]
机构：
[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
[2] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
[3] Philadelphia Coll Osteopath Med, Georgia Campus, Suwanee, GA 30024 USA
[4] Univ Tennessee, Inst Space, Dept Mech Aerosp & Biomed Engn, Tullahoma, TN 37388 USA
[5] SPring 8, JASRI, Tokyo, Hyogo 6795198, Japan
[6] Univ Georgia, Dept Biochem & Mol Biol, Life Sci Bldg, Athens, GA 30602 USA
[7] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Phys Biosci Div, Berkeley, CA 94720 USA
来源：
DALTON TRANSACTIONS | 2016年 / 45卷 / 17期
关键词：
RESONANCE VIBRATIONAL SPECTROSCOPY; DENSITY-FUNCTIONAL THEORY; IRON-SULFUR CLUSTER; 4FE-4S CLUSTER; REORGANIZATION ENERGY; ELECTRONIC-STRUCTURE; ANGSTROM RESOLUTION; 4-IRON FERREDOXIN; NIFE HYDROGENASE; ACTIVE-SITE;
D O I：
10.1039/c5dt04760a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The D14C variant of Pyrococcus furiosus ferredoxin provides an extraordinary framework to investigate a [3Fe-4S] cluster at two oxidation levels and compare the results to its physiologic [4Fe-4S] counterpart in the very same protein. Our spectroscopic and computational study reveals vibrational property changes related to the electronic and structural aspects of both Fe-S clusters.
引用
收藏
页码：7215 / 7219
页数：5
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