Tuning photoactive metal-organic frameworks for luminescence and photocatalytic applications

被引：100
|
作者：
Whelan, Eadaoin [1 ,2 ,3 ]
Steuber, Friedrich W. [1 ,2 ,3 ]
Gunnlaugsson, Thorfinnur [1 ,2 ,3 ,4 ]
Schmitt, Wolfgang [1 ,2 ,3 ]
机构：
[1] Univ Dublin, Trinity Coll, Sch Chem, Dublin 2, Ireland
[2] Univ Dublin, Trinity Coll, SFI AMBER Ctr, Dublin 2, Ireland
[3] Univ Dublin, Trinity Coll, SSPC Res Ctr, Dublin 2, Ireland
[4] Univ Dublin, Trinity Coll, Trinity Biomed Sci Inst TBSI, Dublin 2, Ireland
来源：
COORDINATION CHEMISTRY REVIEWS | 2021年 / 437卷
基金：
欧洲研究理事会; 爱尔兰科学基金会;
关键词：
Metal-organic Frameworks; Porous materials; Photoactive materials; Luminescence; Sensing; Photocatalysis; LIGHT-EMITTING MATERIALS; WHITE-LIGHT; LN-MOFS; WATER OXIDATION; CO2; REDUCTION; THIN-FILMS; NAKED-EYE; HETEROGENEOUS CATALYSTS; DICARBOXYLATE LIGANDS; COORDINATION POLYMERS;
D O I：
10.1016/j.ccr.2020.213757
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Metal-organic frameworks (MOFs) are a class of porous materials, constructed from organic and inorganic components. MOFs have been explored for a diverse range of applications due to their tunable structures, porosities, and properties. This review highlights examples of the applications of photoactive MOFs, with a focus on the effect of MOF components, such as organic linkers, inorganic units and framework guests, on the optical and electronic properties of the materials. Developments in utilising luminescent MOFs as chemical sensors and as light emitting materials are discussed, in addition to recent advances in designing MOF-based photocatalysts for water splitting, CO2 reduction and organic reactions. (C) 2020 Published by Elsevier B.V.
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页数：24
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