Novel pyridyl-stabilised rigid-rod organometallic polymers and their monomeric precursors

被引：32
|
作者：
Adams, CJ [1 ]
James, SL [1 ]
Raithby, PR [1 ]
机构：
[1] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE CB2 1EW,ENGLAND
来源：
CHEMICAL COMMUNICATIONS | 1997年 / 22期
关键词：
D O I：
10.1039/a706586h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of trans-[Pt(NC5H4CHBu2n)(2)Cl-2] 1 with an excess of HC=CR (R = Ph, C6H4Me, C6H4NO2) affords the monomeric complex trans-[Pt(NC5H4CHBu2n)(2)(C=CR)(2)] (R = Ph 2a, C6H4Me 2b, C6H4NO2 2c), the trans arrangement of the alkynyl ligands being confirmed from spectroscopic data and by an X-ray analysis of 2c;when 1 is treated with 1 equiv, of HC=CC6H2(Me)(2)C=CH the polymer [Pt(NC5H4CHBu2n)(2)C=CC6H2Me2C=C](n) is formed, which is soluble in a range of organic solvents.
引用
收藏
页码：2155 / 2156
页数：2
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