Single-crystal structure and magnetic behavior of a molecule-based ferrimagnet Mn[Mn0.2Cr0.8(CN)6]•4H2O

被引：7
|
作者：
Shen, Xiao-Ping
Li, Yi-Zhi
Song, You
Xu, Zheng [1 ]
Guo, Guo-Cong
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212003, Peoples R China
[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 12期
关键词：
Prussian blue analogue; crystal structure; magnetic properties; chromium; manganese;
D O I：
10.1002/ejic.200600062
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compound with the stoichiometry Mn-III[Mn(III)0.2Cr(III)0.8-(CN)(6)]center dot 4H(2)O (1), which was prepared by slow diffusion of an aqueous solution of K-3[Cr(CN)(6)] and a methanol solution of [Mn(saltn)]ClO4 [saltn = N,N'-1,3-propylenebis(sahcylidene-iminato) dianion] through a U-shaped tube containing silica gel, has been characterized by elemental analysis, ICP analysis, XPS, single-crystal X-ray structure analysis, and magnetic measurements. The complex has a face-centered cubic lattice analogous to Prussian blue and indicates ferrimagnetic ordering below T-c = 63 K. (C) Wiley-VCH Verlag GmbH & Co.
引用
收藏
页码：1698 / 1702
页数：5
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