Kinetics and mechanism of the ruthenium(III) catalyzed oxidation of propane-1,3-diol by alkaline hexacyanoferrate(III)

被引：3
|
作者：
Mucientes, AE
Poblete, FJ
Santiago, F
Casado, J
机构：
[1] Univ Castilla La Mancha, Fac Quim, Dept Quim Fis, E-13071 Ciudad Real, Spain
[2] Univ Salamanca, Fac Quim, Dept Quim Fis, E-37008 Salamanca, Spain
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1997年 / 62卷 / 02期
关键词：
kinetics; catalytic oxidation; alcohols; Ru(III);
D O I：
10.1007/BF02475466
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of oxidation of propane-1,3-diol by alkaline hexacyanoferrate (III) catalyzed by ruthenium trichloride has been studied spectrophotometrically. A reaction mechanism involving the formation of an intermediate complex between the substrate and the catalyst is proposed. In the rate-determining step this complex is attacked by hexacyanoferrate (III) forming a free radical which is further oxidized.
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页码：293 / 297
页数：5
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