PdCl2-CUCl2 catalyzed oxidative homocoupling reaction of terminal alkynes in supercritical carbon dioxide

被引：0
|
作者：
Wang, A. [1 ]
Jiang, Huan-Feng [1 ]
机构：
[1] S China Univ Technol, Coll Chem, Guangzhou 510640, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 27卷 / 05期
关键词：
supercritical carbon dioxide; Pd catalyze; oxidative coupling; terminal alkyne; diyne;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
PdCl2-CuCl2 catalyzed oxidative coupling of terminal alkynes in scCO(2) has been developed. The catalyst, supercritical carbon dioxide and its co-solvent have significant influence on the reaction, and the reactivity of the oxidative coupling was affected by the substituent group of terminal alkynes.
引用
收藏
页码：619 / 622
页数：4
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