EPR studies of "self-spin-probing" reactions between the carbanion of nitroalkanes and ω-hydroperfluoro-diacyl peroxides

被引：0

作者：

Zhao, CX ^{[1
]}

Qu, YL ^{[1
]}

Chen, GF ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Coll Chem & Chem Engn, Shanghai 200240, Peoples R China

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2000年 / 26卷 / 04期

关键词：

D O I：

10.1163/156856700X00318

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mechanism of "self-spin-probing'' reactions between carbanion of nitroalkanes (1) and omega-hydroperfluorodiacyl peroxides (2) initiated by electron transfer has been verified by EPR detection of new bis(omega-hydroperfluoro-dialkyl) nitroxides (11) and omega-hydroperfluoroalkyl nitroalkyl nitroxides (12) - spin adducts of radical intermediates H(CF2CF2)(n).(n=1,2,3) and (RRC)-R-1-C-2 . NO2 to the nitroso trap H(CFCF)(n)NO (9) generated in the reactions.

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页码：365 / 374

页数：10

共 4 条

[1] EPR studies of “self-spin-probing” reactions between the carbanion of nitroalkanes and ω-hydroperfluorodiacyl peroxides
C. -X. Zhao
Y. -L. Qu
G. -F. Chen
Research on Chemical Intermediates, 2000, 26 : 365 - 374
[2] THE CHEMISTRY OF DIACYL PEROXIDES .6. ELECTRON-TRANSFER REACTIONS BETWEEN BENZOYL PEROXIDE AND CARBANIONS DERIVED FROM NITROALKANES
ZHAO, CX
QU, YL
JIANG, XK
ACTA CHIMICA SINICA, 1987, 45 (01) : 83 - 86
[3] THE CHEMISTRY OF DIACYL PEROXIDES .7. ELECTRON-TRANSFER REACTIONS BETWEEN CYCLOPROPYLFORMYL PEROXIDE AND CARBANIONS DERIVED FROM SECONDARY NITROALKANES
ZHAO, CX
QU, YL
JIN, XS
JIANG, XK
ACTA CHIMICA SINICA, 1988, 46 (04) : 349 - 352
[4] EPR STUDIES ON ELECTRON-TRANSFER REACTIONS BETWEEN O-BENZOYL-N-ALKYLHYDROXYLAMINES AND PERFLUOROACYL PEROXIDES - GENERATION OF N-ALKYL AND SEC-ALKYL PERFLUOROACYL NITROXIDES AND SEC-ALKYL AND TERT-ALKYL PERFLUOROALKYL NITROXIDES
ZHAO, CX
PENG, YY
QU, YL
RESEARCH ON CHEMICAL INTERMEDIATES, 1992, 18 (01) : 1 - 17

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