Syntheses, structures and properties of three selenoarsenates templated by transition metal complexes

被引：127
|
作者：
Fu, ML
Guo, GC [1 ]
Liu, X
Liu, B
Cai, LZ
Huang, JS
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 01期
基金：
中国国家自然科学基金;
关键词：
selenoarsenates; crystal structure; semiconducting properties; photoluminescence;
D O I：
10.1016/j.inoche.2004.10.021
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three selenoarsenates, [Mn(dien)(2)](3)[As3Se6](2) (dien = C4N3H13) (1), [Fe(en)(3)][As2Se6] (2) and [Mn(en)(3)][As2Se6] (3) (en = C2N2H8), have been synthesized with mild solvothermal route templated by transition metal complexes. The optical absorption spectra as well as photoluminescence of the title compounds are described. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：18 / 21
页数：4
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