Preparation, solution behaviour and X-ray crystal structure of [PtOTf(triphos)]OTf

被引:14
|
作者
Annibale, G
Bergamini, P
Bertolasi, V
Cattabriga, M
Ferretti, V
机构
[1] Univ Ferrara, Dipartmento Chim, I-44100 Ferrara, Italy
[2] Univ Venice, Dipartimento Chim, I-31023 Venice, Italy
关键词
crystal structures; platinum complexes; triphosphine complexes; triflate complexes;
D O I
10.1016/S1387-7003(00)00070-8
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The lability of the coordinated triflate in the new complex [PtOTf(triphos)] OTf both in the solid state and in solution is pointed out by the X-ray crystal structure, by NMR observations and by some examples of nucleophilic substitution at platinum. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:303 / 306
页数:4
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