Chloro-hydroxyl-merocyanine based turn-on fluorescent probes for the detection of hydrazine in water and living cells

被引：0
|
作者：
Li, Kai-Bin [1 ,2 ]
Chen, Yiyu [3 ,4 ,5 ]
Zhou, Tianshuo [3 ,4 ,5 ]
Wang, Tianlin [3 ,4 ,5 ]
Wu, Dian [3 ,4 ,5 ]
Pan, Yuanjiang [1 ]
Zhang, Siqi [2 ]
Shi, Wei [2 ]
Wang, Feiyi [3 ,4 ,5 ]
Ren, Jun [3 ,4 ,5 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
[2] Taizhou Univ, Dept Chem, Jiaojiang 318000, Peoples R China
[3] Hubei Univ, Collaborat Innovat Ctr Adv Organ Chem Mat Coconst, Wuhan 430062, Peoples R China
[4] Hubei Univ, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Peoples R China
[5] Hubei Univ, State Key Lab Biocatalysis & Enzyme Engn, Wuhan 430062, Peoples R China
来源：
DYES AND PIGMENTS | 2022年 / 200卷
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
Fluorescent probe; Hydrazine; Near infrared emission; Image analysis; ANALYTE;
D O I：
10.1016/j.dyepig.2022.110109
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Hydrazine (N2H4) is a very important chemical reagent which has been widely used in the fields of chemistry industry, aerospace, pesticide production and others. However, N2H4 is highly toxic and prone to induce a variety of diseases. Hence, we designed two fluorescent probes (CH-NO1, CH-NO2) based on chloro-hydroxylmerocyanine (CHMC) with similar recognition groups. The two probes were synthesized by a simple reaction coupling between CHMC dye and two alkyl bromine compounds. Both probes showed specific off-on response to N2H4 in aqueous solution with nanomolar LOD (28 nM for CH-NO1 and 38 nM for CH-NO2), and without interference by a range of amino acids, anions and cations. Moreover, CH-NO1 can be used for both environmental and biological monitoring of N2H4.
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页数：6
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