Thermorheological and mechanical properties of cellulose reinforced PLA bio-composites

被引:155
|
作者
Awal, A. [1 ,3 ]
Rana, M. [2 ]
Sain, M. [1 ]
机构
[1] Univ Toronto, Ctr Biocomposites & Biomat Proc, Toronto, ON M5S 3B3, Canada
[2] Tech Univ Dresden, Inst Text Machinery & High Performance Mat Techno, D-01069 Dresden, Germany
[3] Cooper Tire & Rubber Co, Findlay, OH USA
关键词
Bio-composites; PLA; cellulose; Thermorheological properties; Mechanical properties; POLYLACTIC ACID COMPOSITES; POLY(LACTIC ACID); BIODEGRADABLE COMPOSITES; THERMAL-PROPERTIES; FIBER ORIENTATION; NATURAL FIBERS; KENAF FIBERS; PULP; BIOCOMPOSITES; LIGNIN;
D O I
10.1016/j.mechmat.2014.09.009
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Cellulose fibers reinforced polylactic acid (PLA) bio-composites were developed by means of extrusion and injection molding process. The thermal properties of the developed bio-composites were investigated by thermo-gravimetric analysis (TGA). TGA results provided an upper limit of thermal processing window. The rheological properties of bio-composites showed shear thinning behavior and predicted a suitable temperature profile for processing the bio-composites. Heat distortion temperature of PLA/wood fibers (WP)/bioadimide bio-composites was slightly improved which could result in high temperature service life. Good interaction between short fibers and PLA resulted in better mechanical properties. With the addition of 13% bioadimide (bio-additive), tensile strength of bio-composites increased significantly. The impact strength of bio-composites was also considerably increased due to addition of bio-additive with bio-composites. This novel bio-additive was found very effective not only for fiber matrix adhesion but also processability of bio-composites. X-ray computed tomography (CT) demonstrated cellulose fibers orientation and the fiber matrix networking microstructures in a composite system. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:87 / 95
页数:9
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