The electronic structure of oxide ceramics with high-valent manganese, cobalt, nickel and copper - As seen by X-ray absorption spectroscopy (XANES)

被引：0
|
作者：
Reinen, D
Hu, ZW
机构：
[1] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany
[2] Univ Marburg, Zentrum Mat Wissensch, D-35043 Marburg, Germany
[3] Inst Werkstoff Forsch, D-01171 Dresden, Germany
来源：
SOLID STATE CHEMISTRY V | 2003年 / 90-91卷
关键词：
X ray absorption (XANES) spectra; Ni; Co; Cu; Mn oxide ceramics; electronic structure;
D O I：
10.4028/www.scientific.net/SSP.90-91.183
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
X-ray absorption spectroscopy in particular in the XANES version at the ligand L-edge - is a valuable tool in determining the oxidation numbers and electronic structure of transition metal ions in oxidic solids, supplementing EPR and optical spectroscopy. Examples with Co, Ni, Cu and Mn in various oxidation states are discussed. In particular changes in the bond covalency are sensitively imaged.
引用
收藏
页码：183 / 187
页数：5
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