Poly(dimethylsiloxane)-graft-oligo(hexafluoropropeneoxide) via ring-opening polymerization

被引：0
|
作者：
Buese, MA [1 ]
Gonzalez, JF [1 ]
Harbaugh, CG [1 ]
Stearman, GM [1 ]
Williams, MS [1 ]
机构：
[1] Clariant LSM Florida Inc, Gainesville, FL 32602 USA
来源：
SYNTHESIS AND PROPERTIES OF SILICONES AND SILICONE-MODIFIED MATERIALS | 2003年 / 838卷
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cyclotetrasiloxanes with an oligo(hexafluoropropeneoxide) substituent were prepared and ring-opening polymerized. The synthesis of the cyclosiloxanes with three different linkages between the siloxane and fluoroether is described. The cationic and anionic polymerizations were examined. The equilibrium cyclosiloxanes were extracted from the polymer and characterized. The copolymerization with a polycyclosiloxane resulted in the formation of cross-linked networks.
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页码：306 / 317
页数：12
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