Room Temperature Reduction of CO2 to Methanol by Al-Based Frustrated Lewis Pairs and Ammonia Borane

被引：478
|
作者：
Menard, Gabriel [1 ]
Stephan, Douglas W. [1 ]
机构：
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 06期
基金：
加拿大自然科学与工程研究理事会;
关键词：
FREE CATALYTIC-HYDROGENATION; CARBON-DIOXIDE; ACTIVATION; REACTIVITY; B(C6F5)(3); ALUMINUM; IMINES; SYSTEM; H-2;
D O I：
10.1021/ja9104792
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
AlX3 (X = Cl or Br) and PMes(3) (Mes = 2,4,6-C6H2Me3) react to form weak Lewis adducts but also react with CO2 to give Mes(3)P(CO2)(AlX3)(2) (X = Cl; Br). These species react rapidly with excess ammonia borane at room temperature to give CH3OH upon quenching with water.
引用
收藏
页码：1796 / +
页数：4
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