Zeolite-like metal-organic frameworks (ZMOFs): design, synthesis, and properties

被引：664

作者：

Eddaoudi, Mohamed ^{[1
,2
]}

Sava, Dorina F. ^{[2
,3
]}

Eubank, Jarrod F. ^{[2
,4
]}

Adil, Karim ^{[1
]}

Guillerm, Vincent ^{[1
]}

机构：

[1] King Abdullah Univ Sci & Technol, Div Phys Sci & Engn, Adv Membranes & Porous Mat Ctr AMPM, Funct Mat Design Discovery & Dev Res Grp FMD3, Thuwal 239556900, Saudi Arabia

[2] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[3] Sandia Natl Labs, Nanoscale Sci Dept, Albuquerque, NM 87185 USA

[4] Florida Southern Coll, Dept Chem & Phys, Lakeland, FL 33801 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2015年 / 44卷 / 01期

关键词：

CARBON-DIOXIDE CAPTURE; HYDROGEN STORAGE; GAS-ADSORPTION; SODALITE-TYPE; CRYSTAL-STRUCTURE; BUILDING-BLOCKS; IMIDAZOLATE POLYMERS; THERMAL-STABILITY; STRUCTURAL-CHARACTERIZATION; COMPUTATIONAL EVALUATION;

D O I：

10.1039/c4cs00230j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review highlights various design and synthesis approaches toward the construction of ZMOFs, which are metal-organic frameworks (MOFs) with topologies and, in some cases, features akin to traditional inorganic zeolites. The interest in this unique subset of MOFs is correlated with their exceptional characteristics arising from the periodic pore systems and distinctive cage-like cavities, in conjunction with modular intra- and/or extra-framework components, which ultimately allow for tailoring of the pore size, pore shape, and/or properties towards specific applications.

引用

页码：228 / 249

页数：22