Synthesis of ferromagnetic Fe-based bulk glassy alloys in the Fe-Nb-B-Y system

被引:102
|
作者
Song, DS
Kim, JH
Fleury, E
Kim, WT
Kim, DH
机构
[1] Yonsei Univ, Dept Met Engn, Ctr Noncrystalline Mat, Seoul 120749, South Korea
[2] Korea Inst Sci & Technol, Adv Met Res Ctr, Seoul 130650, South Korea
[3] Cheongju Univ, Div Appl Sci, Cheongju 360764, South Korea
关键词
iron-based alloy; glass forming ability; ferromagnetic properties;
D O I
10.1016/j.jallcom.2004.08.014
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effect of substitution of Y for Fe on the glass forming ability (GFA), magnetic and mechanical property has been studied in Fe77-xNb6B17Yx (x = 0-4) alloys. Replacement of 1-4at.% Fe by Y increased the thermal stability of the glass and liquid phase in the Fe-Nb-B-Y alloys. It was found that the Fe74Nb6B17Y3 alloy exhibited the largest T-rg (0.60) and gamma (= T-x/[T-g + T-L])(0.396) values enabling the fabrication of bulk metallic glass (BMG) with a diameter of up to 2 mm. The BMG alloy (greater than or equal to 74 at.% Fe) exhibited high compressive fracture strength and hardness of about 3 GPa and 1060 Hv, respectively. The partial replacement of 3 at.% Fe by Y in Fe-Nb-Y-B improved the alloy magnetization saturation by about 10%. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:159 / 164
页数:6
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