The standard enthalpies of formation of alkoxy-NNO-azoxy compounds

被引:24
|
作者
Kirpichev, E. P. [1 ]
Zyuzin, I. N. [1 ]
Avdonin, V. V. [1 ]
Rubtsov, Yu. I. [1 ]
Lempert, D. B. [1 ]
机构
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
来源
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2006年 / 80卷 / 09期
关键词
D O I
10.1134/S0036024406090019
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The standard enthalpies of combustion Delta H-c(o) and formation Delta(f) H-o of seven alkoxy-NNO-azoxy compounds containing the-N+(O-)=NO-characteristic group were determined by combustion in a calorimetric bomb in the atmosphere of oxygen. The contribution of this group to the Delta(f) H-o enthalpies of the substances studied was calculated. The Delta(f) H-o enthalpies found by the method of group contributions were in satisfactory agreement with experimental data.
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页码:1359 / 1362
页数:4
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