Oxygen-Deficient TiO2-δ Synthesized from MIL-125 Metal-Organic Framework for Photocatalytic Dye Degradation

被引：10
|
作者：
Jawdat, Fanar Hussein [1 ,3 ]
Lin, Jianjian [2 ]
Dou, Shi Xue [1 ]
Park, Min-Sik [4 ]
Nattestad, Andrew [5 ]
Kim, Jung Ho [1 ,4 ]
机构：
[1] Univ Wollongong, AIIM, ISEM, North Wollongong, NSW 2500, Australia
[2] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Shandong, Peoples R China
[3] Univ Baghdad, Coll Engn, Dept Mech Engn, Baghdad, Iraq
[4] Kyung Hee Univ, Dept Adv Mat Engn Informat & Elect, 1732 Deogyeong Daero, Yongin 17104, Gyeonggi Do, South Korea
[5] Univ Wollongong, AIIM, ARC Ctr Excellence Electromat Sci, IPRI, North Wollongong, NSW 2500, Australia
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2019年 / 92卷 / 12期
基金：
新加坡国家研究基金会;
关键词：
Metal organic framework; Rhodamine B (RhB); MIL-125; TIO2; WATER; NANOCOMPOSITES; NANOPARTICLES; NANOMATERIALS; PHOTOANODES; EFFICIENT;
D O I：
10.1246/bcsj.20190238
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two of the biggest limitations for titanium dioxide (TiO2) as a photocatalysis are the lack of visible light response and the need for higher surface areas in order to maximize sites where reactions can take place. In this work, a Metal-Organic Framework (MOF), specifically MIL-125, is employed as a template to produce TiO2 particles with high specific surface area and well-controlled porosity. When annealed under a hydrogen atmosphere to create an oxygen deficient TiO2-delta which is black in appearance, enhanced photocatalytic properties are observed, importantly including a significant visible light response in the degradation of model pollutant Rhodamine B.
引用
收藏
页码：2012 / 2018
页数：7
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