Kinetics of Cl atom reactions with butadienes including isoprene

被引：32
|
作者：
Notario, A
Le Bras, G
Mellouki, A [1 ]
机构：
[1] CNRS, Lab Combust & Syst Reactifs, F-45071 Orleans 2, France
[2] Univ Orleans, F-45071 Orleans, France
[3] Univ Castilla La Mancha, Fac Ciencias Quim, Dept Quim Fis, Ciudad Real 13071, Spain
来源：
CHEMICAL PHYSICS LETTERS | 1997年 / 281卷 / 4-6期
关键词：
D O I：
10.1016/S0009-2614(97)01303-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The laser photolysis-resonance fluorescence technique was used to determine the rate constants for the reactions of Cl atoms with 1,3-butadiene, 2-methyl-1,3 butadiene (isoprene) and 2,3-dimethyl-1,3-butadiene in the pressure range 15-60 Torr and T=(298 +/- 2) K. The obtained rate constants (in units of 10(-10) cm(3) molecule(-1) s(-1)) were as follows: 1,3-butadiene (3.48 +/- 0.10), isoprene (3.61 +/- 0.10) and 2,3-dimethyl-1,3-butadiene (3.63 +/- 0.14). These kinetic data are discussed. (C) 1997 Elsevier Science B.V.
引用
收藏
页码：421 / 425
页数：5
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