Oxidative carbonylation of aniline over a polymer-supported palladium-copper catalyst

被引：10
|
作者：
Wan, BS [1 ]
Liao, SJ [1 ]
Yu, DR [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
来源：
REACTIVE & FUNCTIONAL POLYMERS | 2000年 / 45卷 / 01期
关键词：
polymer-supported bimetallic catalyst; oxidative carbonylation; ethyl N-phenylcarbamate; synergic effect;
D O I：
10.1016/S1381-5148(00)00012-2
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The polymer-supported bimetallic catalyst FVP-PdCl2-2CuCl(2) (PVP, poly(N-vinyl-2-pyrrolidone), obtained in situ by the addition of CuCl2 to an alcoholic solution of PVP-PdCl2, exhibits high selectivity and activity for the oxidative carbonylation of aniline with carbon monoxide and oxygen to ethyl N-phenylcarbamate in the presence of a base (NaOAc) under atmospheric pressure. The strong synergic effect of Pd-Cu gives rise to a clear increase in the selectivity and activity. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：55 / 59
页数：5
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