Formation of cylindrical-shaped coordination polymer by self-assembling of 2, 2, 4, 4, 6, 6-hexakis(4-pyridylmethoxy)-2λ5, 4λ5, 6λ5-cyclotri(phosphazene) with silver nitrate

被引:8
|
作者
Itaya, T [1 ]
Inoue, K [1 ]
机构
[1] Ehime Univ, Fac Engn, Dept Appl Chem, Matsuyama, Ehime 7908577, Japan
关键词
D O I
10.1246/bcsj.73.2615
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The self-assembling of 2, 2, 4, 4, 6, 6-hexakis(4-pyridylmethoxy)-2 lambda (5), 4 lambda (5), 6 lambda (5)-cyclotri(phosphazene) (PyPN) and AgNO3 in DMSO gives a white rod-shaped coordination polymer. FT-LR and X-ray absorption fine structure spectra, X-ray diffraction data, and elemental analysis showed that the coordination polymer takes a cylindrical structure and is laterally packed into a hexagonal arrangement.
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页码:2615 / 2619
页数:5
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