New optically active phosphane ligands with additional ether and hydroxy functionalities were synthesied and used as sources of enantio-selectivity in the Ni-catalyzed cross coupling reaction of 1-phenylethyl Grignard and vinylbromide and in the Pd-catalyzed allylation of 1.5-dimethylbarbituric acid with allyl acetate.
机构:
Univ Bologna, Dept Chem G Ciamician, Alma Mater Studiorum, I-40126 Bologna, ItalyUniv Bologna, Dept Chem G Ciamician, Alma Mater Studiorum, I-40126 Bologna, Italy
Cera, Gianpiero
Bandini, Marco
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机构:
Univ Bologna, Dept Chem G Ciamician, Alma Mater Studiorum, I-40126 Bologna, ItalyUniv Bologna, Dept Chem G Ciamician, Alma Mater Studiorum, I-40126 Bologna, Italy