Enantioselective catalysis CXXI: Chiral phosphane ligands with additional oxygen functionalities

被引:0
|
作者
Brunner, H [1 ]
Ruckert, T [1 ]
机构
[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany
来源
MONATSHEFTE FUR CHEMIE | 1998年 / 129卷 / 04期
关键词
phosphane ligands; enantioselectivity; catalysis; cross coupling; allylation;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New optically active phosphane ligands with additional ether and hydroxy functionalities were synthesied and used as sources of enantio-selectivity in the Ni-catalyzed cross coupling reaction of 1-phenylethyl Grignard and vinylbromide and in the Pd-catalyzed allylation of 1.5-dimethylbarbituric acid with allyl acetate.
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页码:339 / 354
页数:16
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