Di-2-pyridyl ketone oxime in copper chemistry: di-, tri-, penta- and hexanuclear complexes

被引：0
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作者：
Afrati, Tereza
Zaleski, Curtis M.
Dendrinou-Samara, Catherine
Mezei, Gellert
Kampf, Jeff W.
Pecoraro, Vincent L. [1 ]
Kessissoglou, Dimitris P.
机构：
[1] Aristotle Univ Thessaloniki, Dept Gen & Inorgan Chem, GR-54124 Thessaloniki, Greece
[2] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
[3] Shippensburg Univ, Dept Chem, Shippensburg, PA 17257 USA
来源：
DALTON TRANSACTIONS | 2007年 / 25期
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D O I：
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The use of di-2-pyridyl ketone oxime (Hpko)/X- "blends" (X- = OH-, Cl-, ClO4-) in copper chemistry has yielded neutral binuclear and cationic trinuclear, pentanuclear or hexanuclear complexes. Various synthetic procedures have led to the synthesis of compounds [Cu-5(pko)(7)]center dot[ClO4](3)center dot 2CH(3)OH center dot 2H(2)O (1), [Cu-3(pko)(3)(OH)(Cl)](2)[Ph4B](2)center dot 4DMF center dot 2H(2)O (2), [Cu-2(pko)(4)] ( 3), {[Cu-6(pko)(6)ClO4(CH3CN)(6)][Cu-6(pko)(6)(ClO4)(3)(CH3CN)(4)]}center dot 8ClO(4)center dot 14CH(3)CN center dot H2O (4). The structures of the complexes have been determined by single-crystal X-ray crystallography.
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页码：2658 / 2668
页数：11
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