New P2-Na0.70Mn0.60Ni0.30Co0.10O2 Layered Oxide as Electrode Material for Na-Ion Batteries

被引：69

作者：

Yoshida, Jun ^{[1
,2
]}

Guerin, Elodie ^{[1
]}

Arnault, Melissa ^{[1
]}

Constantin, Cedric ^{[1
]}

de Boisse, Benoit Mortemard ^{[1
]}

Carlier, Dany ^{[1
]}

Guignard, Marie ^{[1
]}

Delmas, Claude ^{[1
]}

机构：

[1] ICMCB CNRS, F-33608 Pessac, France

[2] TOYOTA MOTOR EUROPE NV SA, B-1930 Zaventem, Belgium

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2014年 / 161卷 / 14期

关键词：

CATHODE MATERIAL; HIGH-CAPACITY; SODIUM; P2-NA2/3CO2/3MN1/3O2; INTERCALATION; LITHIUM; P2;

D O I：

10.1149/2.0121414jes

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Sodium layered oxide, Na0.70Mn0.60Ni0.30Co0.10O2, with a P2-type structure was synthesized by a co(-)precipitation method and characterized as positive electrode of sodium batteries. The P2-NaxMn0.60Ni0.30Co0.10O2 electrode delivered a high specific capacity of 185 mAh/g in the 1.5-4.3 V range at 1st cycle at C/20 rate; however, rapid capacity decay is observed. In the 1.7-4.0 V range the capacity is equal to 125 mAh/g with a fading considerably reduced. The rate capability is reasonably good. According to the electrochemical profile, a potential plateau around 4.2 V vs. Na+/Na, meaning a bi-phasic domain, and several voltage drops that could be related to single phase domains in a narrow sodium content range are observed. Even if the capacity decreases when the battery is cycled above 4.0 V, there is no irreversible structural change. (C) 2014 The Electrochemical Society. All rights reserved.

引用

页码：A1987 / A1991

页数：5

共 50 条

[1] Designing an advanced P2-Na0.67Mn0.65Ni0.2Co0.15O2 layered cathode material for Na-ion batteries
Li, Zheng-Yao
Gao, Rui
Sun, Limei
Hu, Zhongbo
Liu, Xiangfeng
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (31) : 16272 - 16278
[2] MgO coated P2-Na0.67Mn0.75Ni0.25O2 layered oxide cathode for Na-Ion batteries
Gauckler, Cornelius
Kucinskis, Gints
Pfeiffer, Lukas Fridolin
Abd-El-Latif, Abdelaziz A.
Tang, Yushu
Kuebel, Christian
Maroni, Fabio
Gong, Ruihao
Wohlfahrt-Mehrens, Margret
Axmann, Peter
Marinaro, Mario
JOURNAL OF POWER SOURCES ADVANCES, 2024, 25
[3] Na2Mn3O7: A Suitable Electrode Material for Na-Ion Batteries?
Adamczyk, Evan
Pralong, Valerie
CHEMISTRY OF MATERIALS, 2017, 29 (11) : 4645 - 4648
[4] Na2[Mn3Vac0.1Ti0.4]O7: A new layered negative electrode material for aqueous Na-ion batteries
Wang, Ying
Zhou, FeiYu
Li, Yuanhang
Shi, Peng
Xu, Shuyin
Lyu, Yingchun
Zhu, Chengjun
JOURNAL OF ALLOYS AND COMPOUNDS, 2022, 918
[5] Layered Na2RuO3 as a cathode material for Na-ion batteries
Tamaru, Mao
Wang, Xianfen
Okubo, Masashi
Yamada, Atsuo
ELECTROCHEMISTRY COMMUNICATIONS, 2013, 33 : 23 - 26
[6] Toward Stable Electrode/Electrolyte Interface of P2-Layered Oxide for Rechargeable Na-Ion Batteries
Zarrabeitia, Maider
Chagas, Luciana Gomes
Kuenzel, Matthias
Gonzalo, Elena
Rojo, Teofilo
Passerini, Stefano
Angel Munoz-Marquez, Miguel
ACS APPLIED MATERIALS & INTERFACES, 2019, 11 (32) : 28885 - 28893
[7] β-NaVP2O7 as a Superior Electrode Material for Na-Ion Batteries
Drozhzhin, Oleg A.
Tertov, Ilya V.
Alekseeva, Anastasia M.
Aksyonov, Dmitry A.
Stevenson, Keith J.
Abakumov, Artem M.
Antipov, Evgeny V.
CHEMISTRY OF MATERIALS, 2019, 31 (18) : 7463 - 7469
[8] Na2+xTi6O13 as Potential Negative Electrode Material for Na-Ion Batteries
Shen, Kun
Wagemaker, Marnix
INORGANIC CHEMISTRY, 2014, 53 (16) : 8250 - 8256
[9] P2-Type Na0.67Mn0.65Fe0.20Ni0.15O2 Microspheres as a Positive Electrode Material with a Promising Electrochemical Performance for Na-Ion Batteries
Venkatesh, G.
Kishore, Brij
Viswanatha, R.
Aurbach, Doron
Munichandraiah, N.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2017, 164 (09) : A2176 - A2182
[10] Cobalt-free copper-substituted Na(Ti,Mn,Ni,Cu)O2 layered oxide cathode materials for Na-ion batteries
Milewska, Anna
Zajac, Wojciech
Trenczek-Zajac, Anita
Molenda, Janina
JOURNAL OF SOLID STATE CHEMISTRY, 2022, 315

← 1 2 3 4 5 →