Intercalation of acrylate anions into the galleries of Zn-Al layered double hydroxide

被引：31
|
作者：
Aguzzi, Alessia
Ambrogi, Valeria
Costantino, Umberto
Marmottini, Fabio
机构：
[1] CEMIN, Dipartimento Chim, I-06123 Perugia, Italy
[2] Dipartimento Chim & Tecnol Farmaco, I-06123 Perugia, Italy
[3] Dipartimento Ingn Civile & Ambientale, I-06125 Perugia, Italy
来源：
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2007年 / 68卷 / 5-6期
关键词：
x-ray diffraction; oxides; nanostructures; polymers; thermogravimetric analysis (TGA);
D O I：
10.1016/j.jpcs.2006.12.031
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Acrylate and methacrylate anions containing double bond and carboxylic groups, were intercalated in the interlayer region of a layered double hydroxide of formula: [Zn0.66Al0.34(OH)(2)](NO3)(0.34) 0.62H(2)O. The intercalation compounds obtained have been characterized for their chemical composition and with different instrumental techniques (X-ray powder diffraction, thermal analysis, FT-IR absorption spectroscopy, electron scanning microscopy). Furthermore, they have been used to carry out a preliminary study concerning the in situ polymerization of the intercalated acrylate and methacrylate ions to obtain new interstratified inorgano-organic hybrid materials. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：808 / 812
页数：5
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