Glycerol Esters from Real Waste Cooking Oil Using a Robust Solid Acid Catalyst

被引：5

作者：

Subbiah, Venkatesh ^{[1
]}

van Zwol, Peter ^{[2
]}

Dimian, Alexandre C. ^{[3
]}

Gitis, Vitaly ^{[4
]}

Rothenberg, Gadi ^{[1
]}

机构：

[1] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1098 XH Amsterdam, Netherlands

[2] Solarix BV, NL-2025 ZB Haarlem, Netherlands

[3] Yellow Diesel BV, NL-1000 CM Amsterdam, Netherlands

[4] Ben Gurion Univ Negev, Unit Environm Engn, IL-84105 Beer Sheva, Israel

来源：

TOPICS IN CATALYSIS | 2014年 / 57卷 / 17-20期

关键词：

Heterogeneous catalysis; Waste recycling; Biodiesel; FFA; Sulfated zirconia; BIODIESEL PRODUCTION; SULFATED ZIRCONIA; PROCESS DESIGN; N-BUTANE; ESTERIFICATION; TRANSESTERIFICATION; ACTIVATION; UDCAT-5;

D O I：

10.1007/s11244-014-0337-x

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Notwithstanding the food-for-fuel debate, turning waste cooking oil and fat (WCO) into a valuable product is a classic example of green chemistry. We demonstrate that sulfated zirconia and lanthanum-supported sulfated zirconia are good catalysts for the esterification of WCO free fatty acids (FFAs) with glycerol, giving high-value monoglycerides. Various catalysts were first screened using palmitic acid as a model FFA. Subsequently, six 10-kg batches of actual WCO were collected from commercial cookeries over a period of 28 weeks, pre-treated in a purpose-built decanter and esterified with industrial grade glycerol using heterogeneous catalysis. Good yield and turnovers were obtained. The pre-treatment stage and the catalytic esterification experiments are described and discussed.

引用

页码：1545 / 1549

页数：5

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