tert-Butanesulfinamides as Nitrogen Nucleophiles in Carbon-Nitrogen Bond Forming Reactions

被引：9

作者：

Hernandez, Johana Ramirez ^{[1
]}

Chemla, Fabrice ^{[1
]}

Ferreira, Franck ^{[1
]}

Jackowski, Olivier ^{[1
]}

Oble, Julie ^{[1
]}

Perez-Luna, Alejandro ^{[1
]}

Poli, Giovanni ^{[1
]}

机构：

[1] Univ Paris 06, Sorbonne Univ, UMR CNRS 8232, Inst Parisien Chim Mol, F-75005 Paris, France

来源：

CHIMIA | 2016年 / 70卷 / 1-2期

关键词：

Amination; tert-Butanesulfinamide; Chiral nucleophiles; AZA-MICHAEL REACTION; STEREOSELECTIVE TOTAL-SYNTHESIS; METHYLENE-GAMMA-LACTAMS; ASYMMETRIC-SYNTHESIS; CONVENIENT SYNTHESIS; RACEMIC ALLENYLZINC; COMMON INTERMEDIATE; PRACTICAL SYNTHESIS; CHIRAL AZIRIDINES; CONCISE SYNTHESIS;

D O I：

10.2533/chimia.2016.84

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of tert-butanesulfinamides as nitrogen nucleophiles in carbon-nitrogen bond forming reactions is reviewed. This field has grown in the shadow of the general interest in N-tert-butanesulfinyl imines for asymmetric synthesis and occupies now an important place in its own right in the chemistry of the chiral amine reagent tert-butanesulfinamide. This article provides an overview of the area and emphasizes recent contributions wherein the tert-butanesulfinamides act as chiral auxiliaries or perform as nitrogen donors in metal-catalyzed amination reactions.

引用

页码：84 / 92

页数：9

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