Synthetic studies on azadirachtin: An efficient asymmetric synthesis of the highly functionalized tricyclic decalin part of azadirachtin

被引：0

作者：

Yamamoto, Y ^{[1
]}

Ishihara, J ^{[1
]}

Kanoh, N ^{[1
]}

Murai, A ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan

来源：

SYNTHESIS-STUTTGART | 2000年 / 13期

关键词：

azadirachtin; insect antifeedant; decalin; cyclic carbonate; intramolecular Diels-Alder reaction;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The detailed examination of intramolecular Diels-Alder reactions of several structurally related trienes led to construction of the desired tricyclic decalin moiety of azadirachtin with the alpha -hydroxyl groups at C1 and C3 as well as the oxygenated substituent at C8 in the naturally occurring form in good yields.

引用

页码：1894 / 1906

页数：13

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