Vapor-liquid equilibrium measurements of MTBE and TAME with toluene

被引：5
|
作者：
Vorenberg, DG [1 ]
Raal, JD [1 ]
Ramjugernath, D [1 ]
机构：
[1] Univ KwaZulu Natal, Thermodynam Res Unit, Sch Chem Engn, ZA-4001 Durban, South Africa
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2005年 / 50卷 / 01期
关键词：
D O I：
10.1021/je049867t
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
This paper presents binary vapor-liquid equilibria (VLE) for the ether-aromatic systems including 2-methoxy-2-methylbutane (TAME) and 2-methoxy-2-methylpropane (MTBE) with toluene. The data sets were measured using a dynamic experimental method over a temperature range from (308 to 323) K. The isothermal data were correlated using several liquid-phase excess Gibbs energy models including NRTL, UNIQUAC, and the Wilson model, with the respective model parameters fitted using the Marquardt optimization algorithm. Infinite dilution activity coefficients in the oxygenate-depleted region are reported. The isothermal VLE data are shown to be thermodynamically consistent.
引用
收藏
页码：56 / 59
页数：4
相关论文
共 50 条
  • [1] Vapor-liquid equilibrium measurements for MTBE and TAME with toluene (vol 50, pg 56, 2005)
    Vorenberg, DG
    Raal, JD
    Ramjugernath, D
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (04): : 1499 - 1499
  • [2] VAPOR-LIQUID EQUILIBRIUM MEASUREMENTS.
    Owens, Jonathan L.
    Brady, C.Jeffrey
    Freeman, James R.
    Wilding, W.Vincent
    Wilson, Grant M.
    AIChE Symposium Series, 1987, 83 (256): : 18 - 41
  • [3] Isobaric Vapor-Liquid Equilibrium of Toluene and Cresol Systems
    Kang, Dong-Yuk
    Jang, Hoi-Gu
    Han, Chang-Nam
    Rho, Seon-Gyun
    Cho, Dong Lyun
    Kang, Choon-Hyoung
    KOREAN CHEMICAL ENGINEERING RESEARCH, 2009, 47 (06): : 755 - 761
  • [4] Vapor-liquid equilibrium constants for benzene, toluene, and methylcyclohexane
    不详
    INDUSTRIAL AND ENGINEERING CHEMISTRY, 1944, 36 : 1144 - 1145
  • [5] Determination of high pressure vapor-liquid equilibria. The vapor-liquid equilibrium of benzene-toluene
    Griswold, J
    Andres, D
    Klein, VA
    TRANSACTIONS OF THE AMERICAN INSTITUTE OF CHEMICAL ENGINEERS, 1943, 39 : 0223 - 0240
  • [6] Structural effect on the vapor-liquid equilibrium of toluene-ionic liquid systems
    Yu, Gangqiang
    Jiang, Yifan
    Cheng, Jun
    Lei, Zhigang
    CHEMICAL ENGINEERING SCIENCE, 2019, 198 : 1 - 15
  • [7] VAPOR-LIQUID EQUILIBRIUM MEASUREMENTS OF HFO REFRIGERANT MIXTURES
    Sakoda, Naoya
    Shiheng, Jiang
    Kohno, Masamichi
    Takata, Yasuyuki
    Higashi, Yukihiro
    5TH IIR INTERNATIONAL CONFERENCE ON THERMOPHYSICAL PROPERTIES AND TRANSFER PROCESSES OF REFRIGERANTS (TPTPR), 2017, : 548 - 551
  • [8] VAPOR-LIQUID EQUILIBRIUM MEASUREMENTS OF HFO REFRIGERANT MIXTURES
    Sakoda, Naoya
    Jiang Shiheng
    Kohno, Masamichi
    Takata, Yasuyuki
    Higashi, Yukihiro
    5TH IIR INTERNATIONAL CONFERENCE ON THERMOPHYSICAL PROPERTIES AND TRANSFER PROCESSES OF REFRIGERANTS (TPTPR), 2017, : 1203 - 1206
  • [9] VAPOR-LIQUID EQUILIBRIUM - NEW STILL AND METHOD FOR DETERMINING VAPOR-LIQUID EQUILIBRIUM
    HARPER, BG
    MOORE, JC
    INDUSTRIAL AND ENGINEERING CHEMISTRY, 1957, 49 (03): : 411 - 414
  • [10] VAPOR-LIQUID EQUILIBRIUM OF THE SYSTEM TOLUENE-PYRIDINE-1-BUTANOL
    HOLLO, J
    LENGYEL, T
    INDUSTRIAL AND ENGINEERING CHEMISTRY, 1959, 51 (08): : 957 - 960
12345