Polymerization of styrene with autoxidized methyl linoleate as radical initiator

被引：0
|
作者：
Kondo, M [1 ]
Aikawa, S [1 ]
Tasaka, S [1 ]
Inagaki, N [1 ]
机构：
[1] Shizuoka Univ, Fac Engn, Hamamatsu, Shizuoka 4328011, Japan
来源：
KOBUNSHI RONBUNSHU | 1998年 / 55卷 / 03期
关键词：
methyl linoleate; autoxidation; polymerization; styrene; radical;
D O I：
10.1295/koron.55.130
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Autoxidized methyl linoleate was used as the initiator of radical polymerization of styrene and the influence of the oxidation levels an the structure of resulting polymers a as investigated. Autoxidized methyl linoleate contained mainly monomers and oligomers with hydroperoxide moieties. They are able to work not only as sir. initiator but also as a crosslinking agent for the polymerization of styrene, The polymers synthesized by the oxidized products were not gelled and soluble in polar solvents completely. Therefore, the polymer was assumed to consist of linear (non-closslinked) chains having autoxidized methyl linoleate.
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页码：130 / 136
页数：7
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