Synthesis of perfluoroalkylated benzenes and pyridines through cationic Rh(I)/modified BINAP-catalyzed chemo- and regioselective [2+2+2] cycloaddition

被引：63
|
作者：
Tanaka, Ken [1 ]
Hara, Hiromi [1 ]
Nishida, Goushi [1 ]
Hirano, Masao [1 ]
机构：
[1] Tokyo Univ Agr & Technol, Grad Sch Engn, Dept Appl Chem, Koganei, Tokyo 1848588, Japan
来源：
ORGANIC LETTERS | 2007年 / 9卷 / 10期
关键词：
D O I：
10.1021/ol070456m
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A convenient synthesis of perfluoroalkylated benzenes and pyridines has been achieved by a cationic Rh(I)/modified BINAP-complex-catalyzed chemo- and regioselective [2 + 2 + 2] cycloaddition of alkynes with a perfluoroalkylacetylene and a perfluoroalkylnitrile.
引用
收藏
页码：1907 / 1910
页数：4
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