Kinetics of emulsifier-free emulsion butyl acrylate copolymerization with water-soluble monomers

被引：0

作者：

Kozhevnikov, NV ^{[1
]}

Gol'dfein, MD ^{[1
]}

Terekhina, NV ^{[1
]}

机构：

[1] NG Chernyshevskii State Univ, Saratov, Russia

来源：

CHEMICAL PHYSICS REPORTS | 1997年 / 16卷 / 12期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The effect of temperature, monomer composition, and initiator concentration on the kinetics of emulsifier-free emulsion butyl acrylate copolymerization with acrylonitrile and methacrylic acid, dispersion properties, mechanisms of formation and stabilization of latex particles are studied. It is found that qualitatively the effect of the above-indicated factors on the reactions of chain growth and termination in water is the same as in polymerization in the presence of emulsifier. But the role of the aforesaid elementary reactions in the polymerization process and the conditions of particle stabilization alter, which gives rise to different kinetic effects.

引用

页码：2217 / 2225

页数：9

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