A self-assembled porphyrin-based dimeric capsule constructed by a Pd(II)-pyridine interaction which shows efficient guest inclusion

被引：77

作者：

Ikeda, A ^{[1
]}

Ayabe, M

Shinkai, S

Sakamoto, S

Yamaguchi, K

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8128581, Japan

[2] Chiba Univ, Ctr Chem Anal, Chiba 2638522, Japan

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 23期

关键词：

D O I：

10.1021/ol006620m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Novel self-assembled molecular capsules were constructed from two moles of pyridine-containing porphyrin derivatives and four moles of Pd(II) complexes utilizing a pyridine-Pd(ll) interaction. The H-1 NMR spectral studies established that these self assembled molecular capsules 5 and 6 have a highly symmetrical D-4h structure as well as a large inside cavity. It was shown that molecular capsule 6 can include a large bipyridine guest by a two point simultaneous pyridine-Zn(II) interaction.

引用

页码：3707 / 3710

页数：4

共 7 条

[1] A self-assembled homooxacalix[3]arene-based dimeric capsule constructed by a PdII-pyridine interaction which shows a novel chiral twisting motion in response to guest inclusion
Ikeda, A
Udzu, H
Zhong, ZL
Shinkai, S
Sakamoto, S
Yamaguchi, R
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (17) : 3872 - 3877
[2] A novel self-assembled porphyrin polymer constructed by a Pd(II)-pyridine interaction
Ikeda, A
Ayabe, M
Shinkai, S
CHEMISTRY LETTERS, 2001, (11) : 1138 - 1139
[3] Inclusion of [60]fullerene in a self-assembled homooxacalix[3]arene-based dimeric capsule constructed by a PdII-pyridine interaction.: The Li+-binding to the lower rims can improve the inclusion ability
Ikeda, A
Udzu, H
Yoshimura, M
Shinkai, S
TETRAHEDRON, 2000, 56 (13) : 1825 - 1832
[4] Rational Design of Self-Assembled Cationic Porphyrin-Based Nanoparticles for Efficient Photodynamic Inactivation of Bacteria
Li, Junying
Sun, Wei
Yang, Zihuayuan
Gao, Ge
Ran, Huan-Huan
Xu, Ke-Fei
Duan, Qiu-Yi
Liu, Xiaoyang
Wu, Fu-Gen
ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (49) : 54378 - 54386
[5] A porphyrin-based optical sensor membrane prepared by electrostatic self-assembled technique for online detection of cadmium(II)
Zhao, Lizhi
Zhao, Yaxiang
Li, Rishun
Wu, Dihao
Xu, Rui
Li, Sensen
Zhang, Yuzhong
Ye, Hui
Xin, Qingping
CHEMOSPHERE, 2020, 238 (238)
[6] Construction of a homooxacalix[3]arene-based dimeric capsule cross-linked by a Pd(II)-pyridine interaction
Ikeda, A
Yoshimura, M
Tani, F
Naruta, Y
Shinkai, S
CHEMISTRY LETTERS, 1998, (07) : 587 - 588
[7] Porphyrin-based electrostatically self-assembled multilayers as fluorescent probes for mercury(II) ions: a study of the adsorption kinetics of metal ions on ultrathin films for sensing applications
Caselli, Monica
RSC ADVANCES, 2015, 5 (02) : 1350 - 1358

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