Electrochemical analysis of metal oxides

被引:8
|
作者
Grygar, T [1 ]
Bezdicka, P
Hradil, D
Pikna, L
机构
[1] ASCR, Inst Inorgan Chem, Rez 25068, Czech Republic
[2] Tech Univ Kosice, Kosice 04200, Slovakia
来源
SOLID STATE CHEMISTRY V | 2003年 / 90-91卷
关键词
powder electroanalysis; Fe oxides; Mn oxides;
D O I
10.4028/www.scientific.net/SSP.90-91.45
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Applicability of powder voltammetry to analysis of inorganic solids is demonstrated by the examples of a check of the uniformity of Fe-Cr oxide solid solutions, detection of an amorphous Mn oxide in synthetic Mn-Ni oxide catalyst and natural earthy pigments, and a check of Mn valence in Li-Mn spinel-type oxide with similar to1 mg sample consumption. The reproducibility of the method of powder voltammetry was tested in an interlaboratory trial with three earthy pigments containing mainly Fe2O3 and FeOOH as coloring agents. Powder voltammetry is hence not limited to metal oxides for battery materials, but also to many further oxides of the first row transition metals.
引用
收藏
页码:45 / 49
页数:5
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