Studies on the formation and reactivity of (Na[Fe(CO)2C5H5]2)n

被引：0

作者：

Yan, PF ^{[1
]}

Gao, JS ^{[1
]}

Le, ZY ^{[1
]}

Mao, GJ ^{[1
]}

机构：

[1] Heilongjiang Univ, Dept Chem, Ctr Anal & Testing, Harbin 150080, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 1998年 / 19卷 / 01期

关键词：

polybis(cyclopentadienyldicarbonyliron)sodium; reaction regularity; heteronuclear metal complex;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

According to the reaction of [Fe(CO)(2)C5H5](2) with sodium amalgam(Na/Hg), the molecular structures of crystals and the IR data of L3SnFe (CO)(2)C5H5 (L=C6H11, C6H5), [(C5Me5)(2)Ln(CO)(2)FeC5H5](2) (Ln=Dy, Gd, Sm, Nd, Pr) complexes, the process of forma tion of (Na[Fe(CO)(2)C5H5](2))(n), its structure changes and reaction regularities in the syntheses of heteronuclear metal complexes were analyzed and discussed.

引用

页码：21 / 23

页数：3

共 4 条

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[2] CRYSTAL-STRUCTURES OF BIS(CYCLOPENTADIENYLDICARBONYLIRON)SODIUM TETRAHYDROFURAN AND (CYCLOPENTADIENYLDICARBONYLIRON)SODIUM TETRAMETHYLETHYLENEDIAMINE COMPLEXES
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CHEN, WQ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 377 (01) : 137 - 143
[3] KING RB, 1965, ORGANOMETALLIC SYNTH, V1, P151
[4] LI BH, 1991, CHINESE SCI BULL, V36, P1796

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