Investigation of covalency and spectrum shifts in 3d transition-metal compounds

被引：0

作者：

Gao, FM ^{[1
]}

Zhang, SY

机构：

[1] Yanshan Univ, Qinghuangdao 066004, Peoples R China

[2] Acad Sinica, Changchun Inst Appl Chem, Changchun 130022, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2000年 / 16卷 / 05期

关键词：

3d-electron; chemical bond; covalency; racah parameter; mossbauer isomer shift;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By using a correction factor of d electron effects on bond, PV theory is applied to the calculation of chemical bond;parameters of d transition-metal compounds. Racah parameters and Mossbauer isomer shifts are calculated, and the results are agreement with the experimental values.

引用

页码：751 / 756

页数：6

共 19 条

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