A new theory of the solid-state growth of embryos during nucleation: the fundamental role of interfacial mobility

One of the major challenges in nucleation theory is to explain the kinetic pathway allowing multicomponent precipitates to grow until they reach stability. This problem is particularly challenging when the supersaturation is low, so that the critical size of nucleation is large and requires the condensation of thousands of atoms. A new theory is proposed to explain the growth of embryos before they reach the critical size of nucleation. This theory is not a substitute of the classical nucleation theory, but a complement aiming to understand the kinetic pathway allowing unstable embryos to grow at the expense of their neighbours. The theory stands on the strong interactions between embryos. The latter may exchange atoms via impingement and coarsening, which are possible when there are no concentration gradients between the embryos. This condition is supposed to be met during the unstable growth regime of nucleation considering that the growth is limited by the interface during that period. Assuming that the embryos behave in a collective manner when they are grouped in a cloud, we show that the growth velocity of the most active embryos will be limited only by their interfacial mobility and the available driving force.