Ruthenium complexes bearing amino-bis(phosphinite) or amino-bis(aminophosphine) ligands: Application in catalytic ester hydrogenation

被引：9

作者：

Henrion, Mickael ^{[1
]}

Roisnel, Thierry ^{[1
]}

Couturier, Jean-Luc ^{[2
]}

Dubois, Jean-Luc ^{[3
]}

Sortais, Jean-Baptiste ^{[1
]}

Darcel, Christophe ^{[1
]}

Carpentier, Jean-Francois ^{[1
]}

机构：

[1] Univ Rennes 1, CNRS, Inst Sci Chim Rennes, UMR 6226, F-35042 Rennes, France

[2] Arkema France, CRRA, Rue Henri Moissan, F-69493 Pierre Benite, France

[3] Arkema France, 420 Rue Estienne Orves, F-92705 Colombes, France

来源：

MOLECULAR CATALYSIS | 2017年 / 432卷

关键词：

Ruthenium; Pincer complexes; Homogeneous catalysis; Ester hydrogenation; CNN-PINCER COMPLEXES; EFFICIENT HYDROGENATION; CARBONYL-COMPOUNDS; PHOSPHINE-LIGANDS; CARBOXYLIC ESTERS; DIMETHYL OXALATE; CHIRAL ALCOHOLS; ACID ESTERS; AMINOPHOSPHINE; REDUCTION;

D O I：

10.1016/j.mcat.2017.01.025

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mononuclear hydrido and dinuclear chloro ruthenium(II) complexes derived from readily available amino-bis(phosphinite) and amino(bisaminophosphine) tridentate ligands were applied in the catalytic hydrogenation of ester derivatives. Notably, the cationic ruthenium dimer 2c proved to be an efficient pre-catalyst when used in combination with (KOBu)-Bu-t in THF at 120 degrees C and 50 bar H-2 with aromatic and aliphatic esters. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：15 / 22

页数：8

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