Linear array of cesium atoms assisted by uracil molecules on Au(111)

被引：4

作者：

Wang, Xinyi ^{[1
]}

Ding, Yuanqi ^{[1
]}

Li, Donglin ^{[1
]}

Xie, Lei ^{[1
]}

Xu, Wei ^{[1
]}

机构：

[1] Tongji Univ, Coll Mat Sci & Engn, Interdisciplinary Mat Res Ctr, Shanghai 201804, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 80期

基金：

中国国家自然科学基金;

关键词：

ORGANIC COORDINATION NETWORKS; STRUCTURAL TRANSFORMATION; HYDROGEN-BONDS; METAL; GUANINE; STABILIZATION; ARCHITECTURES; QUARTET; MOTIFS; ALKALI;

D O I：

10.1039/c9cc05709a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Based on STM imaging and DFT calculations, we demonstrate that it is feasible to construct a series of metal-organic U + Cs structures composed of configuration-adjustable multiple-metal-center motifs, which is the consequence of the synergy and competition between hydrogen bonds and ionic bonds. Moreover, assisted by U molecules, the central Cs cations tend to form linear arrays.

引用

页码：12064 / 12067

页数：4

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